Chapter 4: Environmental Oxidation/Reduction & Electrochemistry in Water

2/22/2000


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Table of Contents

Chapter 4: Environmental Oxidation/Reduction & Electrochemistry in Water

Why is this so important environmentally?

What is Redox? It can be expressed as an electron transfer.

Redox Reactions

Half Reactions add to make complete reactions

Oxidation is important in water treatment (ammonium ion to nitrate)

The solubilizing of iron in ìreducing conditionsî

In the Biosphere

Gibbs Free Energy describes where a reaction requires energy to proceed or is spontaneous with its own energy

Rules for determining oxidation numbers

Examples (algebraically)

Alternative rules for oxidation number ID

Example of env. importance

Ex. Redox solubility of Pb in homes

PPT Slide

Env. Standard Metal Concentrations

Corrosion

Corrosion

Fe Corrosion (cont.)

Fe Corrosion (cont.)

Corrosion of Iron in Contact with Water

Corrosion of Iron

PPT Slide

Mechanism of Iron Corrosion

Mechanism of Iron Corrosion

PPT Slide

Corrosion of Iron Prevented by Metal

Galvanization

PPT Slide

PPT Slide

Electrical Potential in a natural water body

PPT Slide

We must understand the process

Author: Duquesne University

Email: kingston@duq.edu